Recently, a professional cinematic crew was asked to produce a commercial for Audi...in infrared using what has to be the first professional-grade digital infrared cinematic camera, made specifically for this job.
This is, to the best of my knowledge, the first instance of a professional cinematic production done in near (refractive) infrared of this kind...
The second may surprise you: the opening sequence of Star Trek: Into Darkness was filmed using a type of digital infrared that mimics the old Kodak Ektachrome EIR (enhanced-colour infrared) film stock, which you can see here.